Please use this identifier to cite or link to this item: http://hdl.handle.net/1959.3/2269

Title

Beyond traditional effective intermolecular potentials and pairwise interactions in molecular simulation

Author(s)

Marcelli, Gianluca;  Todd, B. D.;  Sadus, Richard J.

Abstract

Molecular simulation methods such as Monte Carlo simulation and both equilibrium and nonequilibrium molecular dynamics are powerful computational techniques that allow the exact calculation of molecular properties with minimal approximations. The main approximations are the choice of intermolecular potential and the number of particles involved in each interaction. Typically, only pairwise interactions are counted using a simple effective intermolecular potential such as the Lennard-Jones potential. The use of accurate two-body potentials and calculations that explicitly include three or more body interactions are rare because of the large increase in computational cost involved. Here, we report recent progress in the use of both genuine two-body potentials and calculations involving three-body interactions. We show that in some cases, the contribution of three-body interactions can be accurately estimated from two-body interactions without the increase in computational cost involved in explicitly accounting for three-body interactions. As an example of the benefit of including three-body interactions, the improvement in the prediction of vapour-liquid equilibria is examined.

Publication type

Conference paper

Research centre

Swinburne University of Technology. Centre for Molecular Simulation

Research centre

Swinburne University of Technology. School of Information Technology

Source

Lecture notes in computer science: Proceedings of the International Conference on Computational Science (ICCS 2002), Amsterdam, Netherlands, 21-24 April 2002, Part III, vol. 2331, pp. 932-941

Publication year

2002

Publisher

Springer-Verlag

ISSN

0302-9743 (series ISSN)

ISBN

9783540435945, 3540435948

Publisher URL

http://dx.doi.org/10.1007/3-540-47789-6_98

Peer reviewed